If you're looking to expand the list of armor in the game, the CROSS Cybernetics mod is one to take a look at.
This mod delivers a light version of the game's Power Armor that you construct at a special Cyber Crafting Bench.
There are several different pieces of armor and each of them comes with a significant amount of customization, far more than you get with vanilla armor. There are firmware upgrades, implants, paints, patterns, and more.
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The armor also looks fantastic, like it belongs in the game, an added perk for one of the best Fallout 4 armor mods out there right now.
If you've exhausted all of the armor in the game and you want something new, consider CROSS Cybernetics. We love it.